Advanced Search

Journal Navigation

Journal Home

Subscriptions

Archive

Contact Us

Table of Contents

Click here to sign up for SAGE Journal Email Alerts today!

Sign In to gain access to subscriptions and/or personal tools.
Journal of Dental Research
This Article
Right arrow Abstract Freely available
Right arrow Full Text (PDF)
Right arrow Alert me when this article is cited
Right arrow Alert me if a correction is posted
Right arrow Citation Map
Services
Right arrow Email this article to a friend
Right arrow Similar articles in this journal
Right arrow Similar articles in PubMed
Right arrow Alert me to new issues of the journal
Right arrow Add to Saved Citations
Right arrow Download to citation manager
Right arrowRequest Permissions
Right arrow Request Reprints
Right arrow Add to My Marked Citations
Citing Articles
Right arrow Citing Articles via HighWire
Right arrow Citing Articles via Google Scholar
Right arrow Citing Articles via Scopus
Google Scholar
Right arrow Articles by Olsson, S.
Right arrow Articles by Bergman, M.
Right arrow Search for Related Content
PubMed
Right arrow PubMed Citation
Right arrow Articles by Olsson, S.
Right arrow Articles by Bergman, M.
Right arrowPubmed/NCBI databases
*Compound via MeSH
*Substance via MeSH
Hazardous Substances DB
*COPPER, ELEMENTAL
*INDIUM
*MERCURY COMPOUNDS
*MERCURY, ELEMENTAL
*SILVER COMPOUNDS
*SILVER, ELEMENTAL
*ZINC COMPOUNDS
*ZINC, ELEMENTAL
Medline Plus Health Information
*Mercury
Social Bookmarking
 Add to CiteULike   Add to Complore   Add to Connotea   Add to Del.icio.us   Add to Digg   Add to Reddit   Add to Technorati   Add to Twitter  
What's this?

Release of Elements due to Electrochemical Corrosion of Dental Amalgam

S. Olsson

Department of Dental Materials Science, Faculty of Odontology, University of Umea, Sweden

A. Berglund

Department of Dental Materials Science, Faculty of Odontology, University of Umea, Sweden

M. Bergman

Department of Dental Materials Science, Faculty of Odontology, University of Umea, Sweden

The corrosion pattern of dental amalgam in aqueous media was interpreted theoretically by means of log({alpha}i/{alpha}ref)-pe diagrams. The definitions on which the diagrams were based were given, and their features were described. All sparingly soluble compounds which were expected to be formed in reactions with the solvents considered were listed. All the corrosion products reported in the current literature were found to be formed, and the conditions for their formation were established. It emerged that it was necessary to exclude other sparingly soluble compounds which theoretically might be formed. Two compounds, CuSCN and AgSCN, which have not been reported previously were found to be possible corrosion products. Corrosion products containing mercury compound cannot be formed on amalgam restorations with no metallic contact with other materials.

Key Words: Dental Amalgam • Corrosion • Mercury.

REFERENCES

  • Abraham JE, Svare CW, Frank CW (1984). The effect of dental amalgam restorations on blood mercury levels. J Dent Res 63:71-73.
  • Berglund A., Pohl L., Olsson S., Bergman M. (1988). Determination of the rate of release of intra-oral mercury vapor from amalgam. J Dent Res 67:1235-1242.
  • Berglund A. (1990). Estimation by a 24-hour study of the daily dose of intra-oral mercury vapor inhaled after release from dental amalgam. J Dent Res 69:1646-1651.
  • Berglund A. (1992). Release of mercury vapor from dental amalgam (dissertation). Swed Dent J (Suppl 85):1-95.
  • Berglund A. (1993). An in vitro and in vivo study of the release of mercury vapor from different types of amalgam alloys. J Dent Res 72:939-946.
  • Bergman M. (1992). Release and uptake of mercury from dental amalgam. Proceedings from a State of the art conference on potential biological consequencesof mercury released from dental amalgam, Apr 9-10,1992. Stockholm: Swedish Medical Research Council.
  • Donaldson JD, Moser W., Simpson WB (1963). Basic tin(II) chloride. J Chem Soc ( London):1727-1731.
  • Espevik S. (1977). In vitro corrosion of dental amalgams with different Cu content. Scand J Dent Res 85:631-636.[Medline] [Order article via Infotrieve]
  • Gross MJ, HarrisonJA (1989). Some electrochemical f eaturesof the i vivo corrosion of dental amalgam. J Appl Electrochem 19:301-310.
  • Holland GA, Asgar K. (1974). Some effects on the phases of amalgam induced by corrosion. J Dent Res 53:1245-1254.
  • Jensen SJ (1982). Corrosion products of dental amalgam. Scand J Dent Res 90:239-242.[Medline] [Order article via Infotrieve]
  • Lin J.-HC, Marshall GW, Marshall SJ (1983a). Microstructures of Cu-rich amalgams after corrosion. J Dent Res 62:112-115.
  • Lin J.-HC, Marshall GW Jr, Marshall SJ (1983b). Corrosion product formation sequence on Cu-rich amalgams in various solutions. J Biomed Mater Res 17:913-920.[Medline] [Order article via Infotrieve]
  • Mackert JR Jr (1991). Dental amalgam and mercury. J Am Dent Assoc 122(August):54-61.[Medline] [Order article via Infotrieve]
  • Marek M. (1983). The corrosion of dental materials. In: Treatise on materials science and technology. Vol. 23. Scully JC, editor. London: Academic Press, pp. 331-394.
  • Marshall SJ, Marshall GW Jr (1980). Sn4(OH)6Cl2 and SnO corrosion products of amalgams. J Dent Res 59:820-823.
  • Marshall GW Jr, Jackson BL, Marshall SJ (1980). Copper-rich and conventional amalgam restorations after clinical use. J Am Dent Assoc 100:43-47.[Medline] [Order article via Infotrieve]
  • Marshall SJ, Lin J.-HC, Marshall GW Jr (1982). Cu2O and CuCl2·3Cu(OH)2 corrosion products on copper rich dental amalgams. J Biomed Mater Res 16:81-85.[Medline] [Order article via Infotrieve]
  • Marshall GW Jr, Marshall SJ, Letzel H., Vrijhoef MMA (1987). Microstructures of Cu-rich amalgam restorations with moderate clinical deterioration. Dent Mater 3:135-143.[Medline] [Order article via Infotrieve]
  • Marshall SJ, Marshall GW Jr (1992). Dental amalgam. The materials. Adv Dent Res 6:94-99.[Abstract/Free Full Text]
  • Mateer RS, Reitz CD (1970). Corrosion of amalgam restorations. J Dent Res 49:399-407.
  • Moberg L.-E, Oden A. ( 1985). The microstructure of corroded amalgams. Acta Odontol Scand 43:179-190.[Medline] [Order article via Infotrieve]
  • Olsson S., Berglund A., Pohl L., Bergman M. (1989). Model of mercury vapor transport from amalgam restorations in the oral cavity. J Dent Res 68:504-508.
  • Olsson S., Bergman M. (1992). Daily dose calculations from measurements of intra-oral mercury vapor. J Dent Res 71:414-423.
  • Otani H., Jesser WA, Wilsdorf HGF (1973). The in vivo and in vitro corrosion products of dental amalgams.J Biomed Mater Res 7:523-539.[Medline] [Order article via Infotrieve]
  • Ott KHR, Loh F., Kroncke A., Schaller K-H., Valentin H., Weltle D. (1984). Zur Quecksilberbelastung durch Amalgamfullungen. Dtsch Zahnarztl Z 39:199-205.[Medline] [Order article via Infotrieve]
  • Partington JR (1947). General and inorganic chemistry for university students. London: MacMillan and Co., Limited.
  • Patterson JE, Weissberg BG, Dennison PJ (1985). Mercury in human breath from dental amalgams. Bull Envir Contam Toxicol 34:459-468.
  • Sarkar NK, Marshall GW, Moser JB, Greener EH (1975). In vivo and in vitro corrosion products of dental amalgam. J Dent Res 54:1031-1038.
  • Sillen LG (1952). Redox diagrams. J Chem Ed 29:600-608.
  • Sillen LG, Martell AE (1964). Stability constants of metal-ion complexes. Spec pub No. 17. London: The Chemical Society.
  • Sutow EJ, Jones DW, Hall GC, Owen CG ( 1991). Crevice corrosion products of dental amalgam. J Dent Res 70:1082-1087.
  • Svare CW, Peterson LC, Reinhardt JW, Boyer DB, Frank CW, Gay DD, Cox RD (1981). The effect of dental amalgams on mercury levels in expired air. J Dent Res 60:1668-1671.
  • Tani G., Zucci F. (1967). Electrochemical valuation of the corrosion resistance of commonly used metals in dental prosthesis. Minerva Stomatol 16:710-713.[Medline] [Order article via Infotrieve]
  • Vimy MJ, Lorscheider FL (1985a). Intra-oral air mercury released from dental amalgam. J Dent Res 64:1069-1071.
  • Vimy MJ, Lorscheider FL (1985b). Serial measurements of intra-oral air mercury: Estimation of daily dose from dental amalgam.JDent Res 64:1072-1075.
  • Wald FV, Cocks FH (1971). Investigation of copper-manganese-nickel alloys for dental purposes. J Dent Res 50:48-59.
  • WHO (1991). Environmental health criteria 118. Inorganic mercury. Geneva: World Health Organization.

Journal of Dental Research, Vol. 73, No. 1, 33-43 (1994)
DOI: 10.1177/00220345940730010501


Add to CiteULike CiteULike   Add to Complore Complore   Add to Connotea Connotea   Add to Del.icio.us Del.icio.us   Add to Digg Digg   Add to Reddit Reddit   Add to Technorati Technorati   Add to Twitter Twitter    What's this?


This article has been cited by other articles:


Home page
JDRHome page
S. Olsson, M. Bergman, M. Marek, and A. Berglund
Connections between Polarization Curves and Log(ai/aref)-pe Diagram
Journal of Dental Research, December 1, 1997; 76(12): 1869 - 1878.
[Abstract] [PDF]


Home page
JDRHome page
J.E. Chandler, H.H. Messer, and G. Ellender
Cytotoxicity of Gallium and Indium Ions Compared with Mercuric Ion
Journal of Dental Research, September 1, 1994; 73(9): 1554 - 1559.
[Abstract] [PDF]


This Article
Right arrow Abstract Freely available
Right arrow Full Text (PDF)
Right arrow Alert me when this article is cited
Right arrow Alert me if a correction is posted
Right arrow Citation Map
Services
Right arrow Email this article to a friend
Right arrow Similar articles in this journal
Right arrow Similar articles in PubMed
Right arrow Alert me to new issues of the journal
Right arrow Add to Saved Citations
Right arrow Download to citation manager
Right arrowRequest Permissions
Right arrow Request Reprints
Right arrow Add to My Marked Citations
Citing Articles
Right arrow Citing Articles via HighWire
Right arrow Citing Articles via Google Scholar
Right arrow Citing Articles via Scopus
Google Scholar
Right arrow Articles by Olsson, S.
Right arrow Articles by Bergman, M.
Right arrow Search for Related Content
PubMed
Right arrow PubMed Citation
Right arrow Articles by Olsson, S.
Right arrow Articles by Bergman, M.
Right arrowPubmed/NCBI databases
*Compound via MeSH
*Substance via MeSH
Hazardous Substances DB
*COPPER, ELEMENTAL
*INDIUM
*MERCURY COMPOUNDS
*MERCURY, ELEMENTAL
*SILVER COMPOUNDS
*SILVER, ELEMENTAL
*ZINC COMPOUNDS
*ZINC, ELEMENTAL
Medline Plus Health Information
*Mercury
Social Bookmarking
 Add to CiteULike   Add to Complore   Add to Connotea   Add to Del.icio.us   Add to Digg   Add to Reddit   Add to Technorati   Add to Twitter  
What's this?