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Micro-Raman Line Broadening in Synthetic Carbonated Hydroxyapatite
F.F.M. De Mul
Twente University of Technology, Department of Applied Physics, P.O. Box 217, 7500 AE Enschede, The Netherlands
M.H.J. Hottenhuis
Twente University of Technology, Department of Applied Physics, P.O. Box 217, 7500 AE Enschede, The Netherlands
P. Bouter
Twente University of Technology, Department of Applied Physics, P.O. Box 217, 7500 AE Enschede, The Netherlands
J. Greve
Twente University of Technology, Department of Applied Physics, P.O. Box 217, 7500 AE Enschede, The Netherlands
J. Arends
State University of Groningen, Laboratory Materia Technica, Anthonie Deusinglaan 1, 9713 AV Groningen, The Netherlands
J.J. Ten Bosch
State University of Groningen, Laboratory Materia Technica, Anthonie Deusinglaan 1, 9713 AV Groningen, The Netherlands
Using a Raman microspectrometer, we have recorded Raman spectra of synthetically produced hydroxyapatite samples with varying carbonate contents. The apatites were produced from aqueous solutions at about 40°C. From line-broadening values of the symmetric phosphate stretch, it was concluded that the carbonate substitution in these lattices has a maximum of 4.5 wt %. Both phosphate and hydroxyl ions seem to be involved in the carbonate substitution process.
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Journal of Dental Research, Vol. 65, No. 3,
437-440 (1986)
DOI: 10.1177/00220345860650031301
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