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Solvent Effects on Bonding Organo-silane to Silica Surfaces
T.M. Chen
Food and Drug Administration, Washington, DC
G.M. Brauer
Interfacial bonding and stability of  -methacryloxypropyltrimethoxysilane with silica surfaces have been studied by means of infrared spectroscopy. The addition of n-propylamine enhances silanization of -methacryloxypropyltrimethoxysilane to silica surfaces in normal aliphatic hydrocarbons, and cyclohexane yields a more water-resistant silica-silane bond, and improves the diametral tensile strength of the composite.
REFERENCES
- Kaas, R.L. and Kardos, J.L.: The Interaction of Alkoxy Silane Coupling Agents with Silica Surfaces, Polymer Eng Sci 11:11-18, 1971.[CrossRef]
- Bowen, R.L.: Silica-Resin Direct Filling Material and Method of Preparation, U.S. Pat. 3,194,784, 1965.
- Bascom, W.D.: Structure of Silane Adhesion Promoter Films on Glass and Metal Surfaces, Macromol 5:792-798, 1972.[CrossRef]
- Inoue, H. and Kohama, S.: Effect of Polymer Silane Coupling Agents on Adhesion of Polypropylene and Polystyrene to Glass, J Appl Polymer Sci 19:1939-1954, 1975.[CrossRef]
- Ahagon, A. and Gent, A.N.: Effect of Interfacial Bonding on the Strength of Adhesion, J Polymer Sci, Polymer Phys Ed 13:1285-1300, 1975.[CrossRef]
- Ishida, H. and Koenig, J.L.: Fourier Transform Infrared Spectroscopic Study of the Silane Coupling Agent/Porous Silica Interface, J Colloid Interface Sci 64:555-564, 1978.[CrossRef]
- Koelling, J.G. and Kolb, K.G.: Infrared Study of Reaction Between Alkoxysilanes and Silica, Chem Commun (London) Nov:6-7, 1965.
- Erickson, P.W.: Silane Treatment of Glass Fabric from Nonaqueous Solvents. In: Proc. 24th Annual Tec. Conf. SPI (Soc. Plast. Ind.) Reinf. Plast./Compos. Div, New York, NY: The Society of the Plastics Industry, Inc., 1969, pp. 19-B, 1-10.
- New American Dental Association Specification No. 27 for Direct Filling Resins: Reports of Councils and Bureaus, JADA 94:1191-1194, 1977.
- Hair, M.L.: Infrared Spectroscopy in Surface Chemistry, New York, NY: 1967, pp. 80-84.
- Peri, J.B.: Infrared Study of OH and NH2 Groups on the Surface of a Dry Silica Aerogel, J Phys Chem 70:2937-2945, 1966.[CrossRef]
- Gent, A.N. and Hsu, E.C.: Coupling Reactions of Vinyl-silanes with Silica and Poly(ethylene-co-propylene), Macromol 7:933-936, 1974.[CrossRef]
- Schrader, M.E.: Radioisotopic Studies of Bonding at the Interface, J Adhesion 2:202-212, 1970.[CrossRef]
- CHEN, T.M.: Unpublished data.
- Pauling, L.: The Nature of the Chemical Bond, 2nd ed., Ithaca, NY: Cornell University Press, 1948, p. 59.
- Perrin, D.D.: Dissociation Constants of Organic Bases in Aqueous Solution, London: Butterworths, 1965.
Journal of Dental Research, Vol. 61, No. 12,
1439-1443 (1982)
DOI: 10.1177/00220345820610121301
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