Advanced Search

Journal Navigation

Journal Home

Subscriptions

Archive

Contact Us

Table of Contents

CiteULike is a free service for managing and discovering scholarly references - click here to get started.

Sign In to gain access to subscriptions and/or personal tools.
Journal of Dental Research
This Article
Right arrow Abstract Freely available
Right arrow Full Text (PDF)
Right arrow Alert me when this article is cited
Right arrow Alert me if a correction is posted
Services
Right arrow Email this article to a friend
Right arrow Similar articles in this journal
Right arrow Similar articles in PubMed
Right arrow Alert me to new issues of the journal
Right arrow Add to Saved Citations
Right arrow Download to citation manager
Right arrowRequest Permissions
Right arrow Request Reprints
Right arrow Add to My Marked Citations
Citing Articles
Right arrow Citing Articles via HighWire
Right arrow Citing Articles via Google Scholar
Right arrow Citing Articles via Scopus
Google Scholar
Right arrow Articles by Uzuka, T.
Right arrow Articles by Yasuda, K.
Right arrow Search for Related Content
PubMed
Right arrow PubMed Citation
Right arrow Articles by Uzuka, T.
Right arrow Articles by Yasuda, K.
Right arrowPubmed/NCBI databases
*Compound via MeSH
*Substance via MeSH
Hazardous Substances DB
*COPPER, ELEMENTAL
*GOLD
*SILVER COMPOUNDS
*SILVER, ELEMENTAL
Social Bookmarking
 Add to CiteULike   Add to Complore   Add to Connotea   Add to Del.icio.us   Add to Digg   Add to Reddit   Add to Technorati   Add to Twitter  
What's this?

Determination of the AuCu Superlattice Formation Region in Gold-Copper-Silver Ternary System

Tsutomu Uzuka

Department of Dental Materials Science, School of Dentistry, Tokyo Medical and Dental University, Tokyo 113, Japan

Yasuo Kanzawa

Department of Dental Materials Science, School of Dentistry, Tokyo Medical and Dental University, Tokyo 113, Japan

Katsuhiro Yasuda

Department of Dental Materials Science, School of Dentistry, Tokyo Medical and Dental University, Tokyo 113, Japan

The composition and temperature range of the AuCu-type superlattice formation in the Au-Cu-Ag ternary system was determined by X-ray powder diffraction. Four distinguishable phase transformations were detected, i.e., 1) {alpha} (disordered FCC phase) -> AuCu I, 2) {alpha} -> AuCu II, 3) {alpha} -> {alpha}1 (Cu-rich FCC phase) + {alpha} 2 (Ag-rich FCC phase), and 4) {alpha} -> AuCu3. The stable temperature range of the AuCu I-type superlattice was restricted to a lower temperature range by adding silver to stoichiometric and off-stoichiometric Au-Cu alloys. Depending on the increase in silver content, the co-existing region of the AuCu II-type superlattice and the silver-rich {alpha}2 phase extended to the lower temperature and over a wide composition range.

REFERENCES

  • Masing, G. and Kloiber, K.: Ausscheidungsvorgange im System Kupfer-Silber-Gold, Z Metallkunde 32:125-132, 1940.
  • McMullin, J. and Norton, J.: On the Structure of Gold-Silver-Copper Alloys, Metals Trans 1:46-48, 1949.
  • Murakami, M.; De Fontaine, D.; Sanchez, J.; and Fodor, J.: Ternary Diffusion in Multilayer Ag-Au-Cu Thin Films, Thin Solid Films 25:465-482, 1975.[CrossRef]
  • Sanchez, J.; et al.: Cluster Approach to Order and Disorder, presented at AIME Symposium, Feb. 1979, Proc AIME Symp, in press.
  • Kanzawa, Y.; Yasuda, K.; and Metahi, H.: Structural Changes Caused by Age-hardening in a Dental Gold Alloy, J Less-Common Met 43:121-128, 1975.
  • Yasuda, K. and Kanzawa, Y.: Electron Microscope Observation in an Age-hardenable Dental Gold Alloy, Trans Jpn Inst Met 18: 46-54,1977.
  • Yasuda, K.; Metahi, H.; and Kanzawa, Y.: Structure and Morphology of an Age-hardened Gold-Copper-Silver Alloy, J Less-Common Met 60:P65-P78, 1978.
  • Yasuda, K. and Ohta, M.: Age-hardening in a 14-carat Dental Gold Alloy, presentation at the 3rd International Precious Metals Conf., Chicago, May 9, 1979, Proc IPMI, in press.
  • Prasad, A.; Eng, T.; and Mukherjee, K.: Electron-microscopic Studies of Hardening in Type III Dental Alloy, Mater Sci Eng 24:179-185,1976.[CrossRef]
  • Johansson, C. and Linde, J.: Rontogenographische und Elektrische Untersuchungen des CuAu-Systems, Ann Physik 25:1-48, 1936.[CrossRef]
  • Sato, H. and Toth, R.: Effect of Additional Elements on the Period of AuCu II and the Origin of the Long-period Superlattice, Phys Rev 124:1833-1847, 1961.[CrossRef]
  • Raub, E.: Der Einfluβ des Silbers auf die Umwandlungen des System Gold-Kupfer, Z Metallkunde 40:46-54, 1949.
  • Shashikov, 0.; Syutkina, V.; and Rudenko, V.: Influence of Atomic Ordering on the Process of Decomposition in a Gold-Copper-Silver Alloy, Phys Met Metallogr 37:94-100, 1974.
  • Raub, E. and Worwag, G.: Über Gold-Palladium-Kupfer-Legierungen,Z Metallkunde 46:119-128,1955.
  • Hayashi, I.: Effect of Platinum Addition to the AuCu Transformation, J Jpn Soc Dent Appar Mater 16:161-167, 1975 (in Japanese with English summary).
  • Hultgren, R. and Tarnopol, L.: Effect of Silver on the Gold-Copper-Superlattice AuCu, Trans Met Soc AIME 133:228-238, 1939.

Journal of Dental Research, Vol. 60, No. 5, 883-889 (1981)
DOI: 10.1177/00220345810600050501


Add to CiteULike CiteULike   Add to Complore Complore   Add to Connotea Connotea   Add to Del.icio.us Del.icio.us   Add to Digg Digg   Add to Reddit Reddit   Add to Technorati Technorati   Add to Twitter Twitter    What's this?


This article has been cited by other articles:


Home page
JDRHome page
P.P. Corso Jr, R.M. German, and H.D. Simmons Jr
Corrosion Evaluation of Gold-based Dental Alloys
Journal of Dental Research, May 1, 1985; 64(5): 854 - 859.
[Abstract] [PDF]


Home page
JDRHome page
H. Hero, R. Jorgensen, and E. Sorbroden
A Low-gold Dental Alloy: Structure and Segregations
Journal of Dental Research, November 1, 1982; 61(11): 1292 - 1298.
[Abstract] [PDF]


Home page
JDRHome page
K. Yasuda and M. Ohta
Difference in Age-hardening Mechanism in Dental Gold Alloys
Journal of Dental Research, March 1, 1982; 61(3): 473 - 479.
[Abstract] [PDF]


This Article
Right arrow Abstract Freely available
Right arrow Full Text (PDF)
Right arrow Alert me when this article is cited
Right arrow Alert me if a correction is posted
Services
Right arrow Email this article to a friend
Right arrow Similar articles in this journal
Right arrow Similar articles in PubMed
Right arrow Alert me to new issues of the journal
Right arrow Add to Saved Citations
Right arrow Download to citation manager
Right arrowRequest Permissions
Right arrow Request Reprints
Right arrow Add to My Marked Citations
Citing Articles
Right arrow Citing Articles via HighWire
Right arrow Citing Articles via Google Scholar
Right arrow Citing Articles via Scopus
Google Scholar
Right arrow Articles by Uzuka, T.
Right arrow Articles by Yasuda, K.
Right arrow Search for Related Content
PubMed
Right arrow PubMed Citation
Right arrow Articles by Uzuka, T.
Right arrow Articles by Yasuda, K.
Right arrowPubmed/NCBI databases
*Compound via MeSH
*Substance via MeSH
Hazardous Substances DB
*COPPER, ELEMENTAL
*GOLD
*SILVER COMPOUNDS
*SILVER, ELEMENTAL
Social Bookmarking
 Add to CiteULike   Add to Complore   Add to Connotea   Add to Del.icio.us   Add to Digg   Add to Reddit   Add to Technorati   Add to Twitter  
What's this?