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Journal of Dental Research
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*Compound via MeSH
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*2-HYDROXYETHYL METHACRYLATE
*CALCIUM COMPOUNDS
*CALCIUM, ELEMENTAL
*SILICON CARBIDE
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Biomaterials & Bioengineering

Nano DCPA-Whisker Composites with High Strength and Ca and PO4 Release

H.H.K. Xu1,*, L. Sun1, M.D. Weir1, J.M. Antonucci2, S. Takagi1, L.C. Chow1 and M. Peltz2

1 Building 224, Room A-153, Stop 8546, Paffenbarger Research Center, American Dental Association Foundation and
2 National Institute of Standards and Technology, Gaithersburg, MD 20899-8546, USA

Correspondence: * corresponding author, hockin.xu{at}nist.gov

The main challenges facing composite restorations are secondary caries and bulk fracture. The objective of this study was to develop nano DCPA (dicalcium phosphate anhydrous)-whisker composites with high strength and Ca and PO4 ion release to combat caries. Flexural strength for the nano DCPA-whisker composites at a nano DCPA:whisker mass ratio of 1:2 ranged from (148 ± 9) MPa to (167 ± 23) MPa, significantly higher than the (103 ± 32) MPa of an inlay/onlay commercial control composite without Ca-PO4 release. The nano DCPA-whisker composite released PO4 to a concentration of (1.95 ± 0.13) mmol/L and Ca of (0.68 ± 0.05) mmol/L. Compared with previous conventional Ca- and PO4-releasing composites, the nano DCPA-whisker composites had strengths two-fold higher, and released comparable or higher levels of Ca and PO4. In conclusion, combining nano-DCPA with whiskers yielded novel composites that released high levels of Ca and PO4 requisite for remineralization. These high-strength composites may provide a unique combination of stress-bearing and caries-inhibiting capabilities.

Key Words: dental resin composite • nano particles • whiskers • strength • Ca and PO4 ion release

Journal of Dental Research, Vol. 85, No. 8, 722-727 (2006)
DOI: 10.1177/154405910608500807


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