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Journal of Dental Research
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*Compound via MeSH
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*GALLIUM
*INDIUM
*SILVER COMPOUNDS
*SILVER, ELEMENTAL
*TIN
*TIN COMPOUNDS
*TIN OXIDE
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ESCA Study on Dental Alloy Surfaces Modified by Ga-Sn Alloy

H. Ohno

Department of Dental Materials Science, Higashi-Nippon-Gakuen University, 061-02, Ishikari-Tobetsu, Hokkaido, Japan

Y. Araki

Department of Dental Materials Science, Higashi-Nippon-Gakuen University, 061-02, Ishikari-Tobetsu, Hokkaido, Japan

K. Endo

Department of Dental Materials Science, Higashi-Nippon-Gakuen University, 061-02, Ishikari-Tobetsu, Hokkaido, Japan

A new, simple surface modification method for adherend metals has been developed. It gives high bond strength and superior water durability to dental precious-metal alloys bonded with 4-META/ MMA-TBB resin. However, there was no effect on the bonding of Ag-In-Zn alloy and base-metal alloys. In the present study, the alloy surfaces modified by the new method were analyzed by ESCA and SEM for determination of details of the modification effect.

A new alloying layer containing Ga and Sn was formed on the precious-metal alloys. The main factor for excellent adhesion to be achieved was the formation of a very thin layer of Ga 2O3 and SnO2, less than 1-2 nm thick, on the alloy surface. A thicker modified layer, as formed on the Ag-In-Zn and Ni-Cr alloys, led to low bonding ability.

Journal of Dental Research, Vol. 71, No. 6, 1332-1339 (1992)
DOI: 10.1177/00220345920710061101


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H. Ohno, Y. Araki, and K. Endo
A New Method for Promoting Adhesion between Precious Metal Alloys and Dental Adhesives
Journal of Dental Research, June 1, 1992; 71(6): 1326 - 1331.
[Abstract] [PDF]