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Journal of Dental Research
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*MERCURY COMPOUNDS
*MERCURY, ELEMENTAL
*SILVER COMPOUNDS
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*TIN
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Potential Sweep and Intensiostatic Pulse Studies of Sn, Sng Hg and Dental Amalgam in Chloride Solution

H. Do Duc

Université de Genève, Département de chimie minérale, analytique et appliquée, 30 Quai Ernest-Ansermet, 1211 GENEVA 4, Switzerland

P. Tissot

Université de Genève, Département de chimie minérale, analytique et appliquée, 30 Quai Ernest-Ansermet, 1211 GENEVA 4, Switzerland

J.-M. Meyer

Université de Genéve, Ecole de Médecine Dentaire, 19, rue Barthelemy-Menn, 1211 GENEVA 4, Switzerland

The anodic behavior of the Sn, the Sn8Hg ({gamma}2) phase and the dental amalgam in a chloride solution has been investigated by means of the linear potential sweep and of the intensiostatic pulse method. The results indicate that anodic current varies with chloride concentration and that dissolution occurs prior to passivation of the electrode. The anodic charge needed for the passivation is smallest for the dental amalgam.

Journal of Dental Research, Vol. 58, No. 2, 576-583 (1979)
DOI: 10.1177/00220345790580020601
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S. J. Marshall and G. W. Marshall JR
Sn4(OH)6Cl2 and SnO Corrosion Products of Amalgams
Journal of Dental Research, May 1, 1980; 59(5): 820 - 823.
[Abstract] [PDF]