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Journal of Dental Research
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*CALCIUM COMPOUNDS
*CALCIUM, ELEMENTAL
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Improved Adhesion of Acrylic Restorative Materials to Dental Enamel by Precoating with Monomers Containing Phosphonate Groups

Eldon P. Farley

Stanford Research Institute, Menlo Park, California 94035, USA

Robin L. Jones

Stanford Research Institute, Menlo Park, California 94035, USA

Michael Anbar

Stanford Research Institute, Menlo Park, California 94035, USA

The adhesion of acrylic composite restorative materials to etched dental enamel is increased by a factor of two or more when the enamel is coated with a thin layer of vinylbenzyl phosponic acid (VBPA) prior to forming the enamel-restorative bond. The present results support the suggestion that the enhanced adhesion is attributable to bonding between calcium ions in the enamel surface and phosphonate groups in the VBPA.

Journal of Dental Research, Vol. 56, No. 8, 943-952 (1977)
DOI: 10.1177/00220345770560082001
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J. R. Jedrychowski, A. A. Caputo, and R. Foliart
Effects of Adhesion Promoters on Resin-enamel Retention
Journal of Dental Research, April 1, 1979; 58(4): 1371 - 1376.
[Abstract] [PDF]