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Journal of Dental Research
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Kinetics of Crystal Growth and Dissolution of Calcium and Magnesium Fluorides

G.L. Gardner

Chemistry Department, State University of New York at Buffalo, Buffalo, New York 14214, USA

G.H. Nancollas

Chemistry Department, State University of New York at Buffalo, Buffalo, New York 14214, USA

The crystal growth and dissolution of calcium fluoride and magnesium fluoride are controlled by a reaction at the crystal surface. The activation energy for growth and dissolution of calcium fluoride was found to be 14.5 and 17.4 kcal mole-1, respectively, and the heat of solution, obtained from separate calorimetric experiments was 2.9 ± 0.1 kcal mole-1.

Journal of Dental Research, Vol. 55, No. 3, 342-352 (1976)
DOI: 10.1177/00220345760550030901
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Z. Amjad, P.G. Koutsoukos, and G.H. Nancollas
The Remineralization of Fluoride-treated Bovine Enamel Surfaces
Journal of Dental Research, September 1, 1982; 61(9): 1094 - 1098.
[Abstract] [PDF]