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Journal of Dental Research
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SnHPO 4 from the Reaction of Stannous Fluoride and Hydroxyapatite at a Low pH

K.G. Nelson

College of Pharmacy, University of Minnesota, Minneapolis, Minnesota 55455, USA

C.A. Bainbridge

College of Pharmacy, University of Minnesota, Minneapolis, Minnesota 55455, USA

The reaction of stannous fluoride with hydroxyapatite at pH values less than 2 was studied. The X-ray diffraction powder pattern indicates that the major product is SnHPO 4. Chemical analysis corroborated this finding and also indicated a minor amount of calcium and fluoride. SnHP04 was synthesized and its X-ray pattern was compared with the reaction product.

Journal of Dental Research, Vol. 52, No. 2, 318-321 (1973)
DOI: 10.1177/00220345730520022101
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K. G. Nelson
Rate of Stannous Fluoride Reaction with Hydroxyapatite
Journal of Dental Research, January 1, 1978; 57(1): 162 - 165.
[Abstract] [PDF]

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S.K. Doss
Surface Properties of Hydroxyapatite : I. The Effect of Various Inorganic Ions on the Electrophoretic Behavior
Journal of Dental Research, November 1, 1976; 55(6): 1067 - 1075.
[Abstract] [PDF]